美国化学会志(JACS)2013-09-05 2:57 AM

Detection of Isomeric Microscopic Host–Guest Complexes. A Time-Evolving Cucurbit[7]uril Complex - Journal of the American Chemical Society (ACS Publications)

The formation of inclusion complexes between the cucurbit[7]uril host and a cationic guest containing ferrocenylmethyl and adamantyl residues connected to an ammonium nitrogen initially leads to an 1:1 mixture of two isomeric microscopic complexes, which evolves as a function of time toward the thermodynamically stable mixture, dominated by the adamantyl-included complex.

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