Nature2014-06-09 4:40 PM

镍在小分子合成方面的应用  Recent advances in homogeneous nickel catalysis 

论文摘要  

镍是一种重要催化剂,自上个世纪70年代以来有机化学家对其特别感兴趣,既用它来催化交叉偶联反应,也用它来催化烯烃和炔烃的一系列反应。这篇Review文章关注均相镍催化在小分子合成上的应用方面所取得的最新进展,包括由镍介导的交叉偶联反应和C-H键激发反应。

Abstract 

Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions. In recent years, these properties have been increasingly understood and used to perform transformations long considered exceptionally challenging. Here we discuss some of the most recent and significant developments in homogeneous nickel catalysis, with an emphasis on both synthetic outcome and mechanism. 

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